Perfect Couples ♔ Angelina Jolie & Brad Pitt
           Angelina Jolie and Brad Pitt met on the set of “Mr and Mrs Smith” in 2005 while he was still married to Jennifer Aniston. The chemistry between them was so great that months after he announced his divorce and took the relationship with Angelina. The couple has six children, three adopted and three biological. Brad and Angie are not married officially.